Los científicos han descubierto que el tantalio, un metal superconductor, mejora significativamente el rendimiento de los qubits en las computadoras cuánticas. Usando espectroscopía de fotoelectrones de rayos X, encontraron que la capa de óxido de tantalio en los qubits no era uniforme, lo que llevó a más investigaciones sobre cómo modificar estas interfaces para aumentar el rendimiento general del dispositivo.
Los investigadores decodifican el perfil químico de los óxidos de superficie de tantalio para mejorar la comprensión de los mecanismos de pérdida y aumentar el rendimiento de los cúbits.
Ya sea hornear un pastel, construir un edificio o crear un dispositivo cuántico, el calibre del producto terminado está muy influenciado por los componentes o materiales fundamentales utilizados. En su búsqueda por mejorar el rendimiento de los qubits superconductores, que forman la base de las computadoras cuánticas, los científicos han estado investigando diferentes materiales fundamentales con el objetivo de extender la vida útil coherente de estos qubits.
El tiempo de coherencia sirve como una métrica para determinar cuánto tiempo un qubit puede conservar los datos cuánticos, lo que lo convierte en un indicador clave de rendimiento. Una revelación reciente de los investigadores ha demostrado que el uso de tantalio en qubits superconductores aumenta su funcionalidad. Sin embargo, las razones subyacentes seguían siendo desconocidas, hasta ahora.
Los científicos del Centro de Nanomateriales Funcionales (CFN), la Fuente Nacional de Luz Sincrotrón II (NSLS-II), el Centro de Codiseño para la Ventaja Cuántica (C2QA) y la Universidad de Princeton han investigado las razones fundamentales por las que estos qubits funcionan mejor en la decodificación. el perfil químico del tantalio.
Los resultados de este trabajo, publicado recientemente en la revista ciencia avanzada, proporcionará conocimientos esenciales para diseñar cúbits aún mejores en el futuro. CFN y NSLS-II son la Oficina de Instalaciones para Usuarios Científicos del Departamento de Energía de EE. UU. (DOE) en el Laboratorio Nacional Brookhaven del DOE. C2QA es un centro nacional de investigación en ciencia de la información cuántica dirigido por Brookhaven, del cual[{» attribute=»»>Princeton University is a key partner.
Finding the right ingredient
Tantalum is a unique and versatile metal. It’s dense, hard, and easy to work with. Tantalum also has a high melting point and is resistant to corrosion, making it useful in many commercial applications. In addition, tantalum is a superconductor, which means it has no electrical resistance when cooled to sufficiently low temperatures, and consequently can carry current without any energy loss.
Tantalum-based superconducting qubits have demonstrated record-long lifetimes of more than half a millisecond. That is five times longer than the lifetimes of qubits made with niobium and aluminum, which are currently deployed in large-scale quantum processors.
Tantalum oxide (TaOx) being characterized using X-ray photoelectron spectroscopy. Credit: Brookhaven National Laboratory
These properties make tantalum an excellent candidate material for building better qubits. Still, the goal of improving superconducting quantum computers has been hindered by a lack of understanding as to what is limiting qubit lifetimes, a process known as decoherence. Noise and microscopic sources of dielectric loss are generally thought to contribute; however, scientists are unsure exactly why and how.
“The work in this paper is one of two parallel studies aiming to address a grand challenge in qubit fabrication,” explained Nathalie de Leon, an associate professor of electrical and computer engineering at Princeton University and the materials thrust leader for C2QA. “Nobody has proposed a microscopic, atomistic model for loss that explains all the observed behavior and then was able to show that their model limits a particular device. This requires measurement techniques that are precise and quantitative, as well as sophisticated data analysis.”
Surprising results
To get a better picture of the source of qubit decoherence, scientists at Princeton and CFN grew and chemically processed tantalum films on sapphire substrates. They then took these samples to the Spectroscopy Soft and Tender Beamlines (SST-1 and SST-2) at NSLS-II to study the tantalum oxide that formed on the surface using x-ray photoelectron spectroscopy (XPS). XPS uses X-rays to kick electrons out of the sample and provides clues about the chemical properties and electronic state of atoms near the sample surface. The scientists hypothesized that the thickness and chemical nature of this tantalum oxide layer played a role in determining the qubit coherence, as tantalum has a thinner oxide layer compared to the niobium more typically used in qubits.
“We measured these materials at the beamlines in order to better understand what was happening,” explained Andrew Walter, a lead beamline scientist in NSLS-II’s soft x-ray scattering & spectroscopy program. “There was an assumption that the tantalum oxide layer was fairly uniform, but our measurements showed that it’s not uniform at all. It’s always more interesting when you uncover an answer you don’t expect, because that’s when you learn something.”
The team found several different kinds of tantalum oxides at the surface of the tantalum, which has prompted a new set of questions on the path to creating better-superconducting qubits. Can these interfaces be modified to improve overall device performance, and which modifications would provide the most benefit? What kinds of surface treatments can be used to minimize loss?
Embodying the spirit of codesign
“It was inspiring to see experts of very different backgrounds coming together to solve a common problem,” said Mingzhao Liu, a materials scientist at CFN and the materials subthrust leader in C2QA. “This was a highly collaborative effort, pooling together the facilities, resources, and expertise shared between all of our facilities. From a materials science standpoint, it was exciting to create these samples and be an integral part of this research.”
Walter said, “Work like this speaks to the way C2QA was built. The electrical engineers from Princeton University contributed a lot to device management, design, data analysis, and testing. The materials group at CFN grew and processed samples and materials. My group at NSLS-II characterized these materials and their electronic properties.”
Having these specialized groups come together not only made the study move smoothly and more efficiently, but it gave the scientists an understanding of their work in a larger context. Students and postdocs were able to get invaluable experience in several different areas and contribute to this research in meaningful ways.
“Sometimes, when materials scientists work with physicists, they’ll hand off their materials and wait to hear back regarding results,” said de Leon, “but our team was working hand-in-hand, developing new methods along the way that could be broadly used at the beamline going forward.”
Reference: “Chemical Profiles of the Oxides on Tantalum in State of the Art Superconducting Circuits” by Russell A. McLellan, Aveek Dutta, Chenyu Zhou, Yichen Jia, Conan Weiland, Xin Gui, Alexander P. M. Place, Kevin D. Crowley, Xuan Hoang Le, Trisha Madhavan, Youqi Gang, Lukas Baker, Ashley R. Head, Iradwikanari Waluyo, Ruoshui Li, Kim Kisslinger, Adrian Hunt, Ignace Jarrige, Stephen A. Lyon, Andi M. Barbour, Robert J. Cava, Andrew A. Houck, Steven L. Hulbert, Mingzhao Liu, Andrew L. Walter and Nathalie P. de Leon, 11 May 2023, Advanced Science.
DOI: 10.1002/advs.202300921
